Light-Off in Plasmon-Mediated Photocatalysis

Plasmon enhanced visible light photocatalysis for TiO2 supported Pd nanoparticles.

A photocatalyst consisting of nanostructured Pd photochemically deposited on 20 nm TiO2 displays a reaction half-life for rhodamine b decolourisation of 0.5 minute compared to the 9.4 minutes for unmodified P25 under identical reaction conditions. We associate this increased decolourisation rate to the increase in solar light harvesting which we have measured at 8% due to a significant red shif...

Plasmonic Photocatalysis: Plasmon‐Mediated Solar Energy Conversion via Photocatalysis in Noble Metal/Semiconductor Composites (Adv. Sci. 6/2016)

Evidence and implications of direct charge excitation as the dominant mechanism in plasmon-mediated photocatalysis

Plasmonic metal nanoparticles enhance chemical reactions on their surface when illuminated with light of particular frequencies. It has been shown that these processes are driven by excitation of localized surface plasmon resonance (LSPR). The interaction of LSPR with adsorbate orbitals can lead to the injection of energized charge carriers into the adsorbate, which can result in chemical trans...

Plasmon‐Mediated Solar Energy Conversion via Photocatalysis in Noble Metal/Semiconductor Composites

Plasmonics has remained a prominent and growing field over the past several decades. The coupling of various chemical and photo phenomenon has sparked considerable interest in plasmon-mediated photocatalysis. Given plasmonic photocatalysis has only been developed for a relatively short period, considerable progress has been made in improving the absorption across the full solar spectrum and the...

Visible-light-induced photocatalysis through surface plasmon excitation of gold on titania surfaces.

Fifteen commercial titania (titanium(iv) oxide; TiO(2)) powders were modified with gold by photodeposition to prepare photocatalysts that work under irradiation with light in the visible range (vis). The gold-modified titania (Au/TiO(2)) powders were characterized by diffuse reflectance spectroscopy (DRS), field-emission scanning electron microscopy (FE-SEM), scanning transmission microscopy (S...